Selective CO<sub>2</sub> Adsorption in a Robust and Water-Stable Porous Coordination Polymer with New Network Topology
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https://figshare.com/articles/dataset/Selective_CO_sub_2_sub_Adsorption_in_a_Robust_and_Water_Stable_Porous_Coordination_Polymer_with_New_Network_Topology/2567209
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资源简介:
A robust and water-stable porous coordination polymer
[Cd(NDC)0.5(PCA)]·Gx (1) (H2NDC = 2,6-napthalenedicarboxylic acid, HPCA
= 4-pyridinecarboxylic
acid, G = guest molecules) with new network topology has been synthesized
solvothermally. The framework is 3D porous material and forms a 1D
channel along the c-axis, with the channel dimensions
∼9.48 × 7.83 Å2. The compound has high
selectivity in uptake of CO2 over other gases (H2, O2, Ar, N2, and CH4). The framework
is highly stable in presence of water vapor even at 60 °C. The
high CO2 selectivity over other gases and water stability
makes the compound promising candidate for industrial postcombustion
gas separation application.
创建时间:
2012-01-02



