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Novel Synthesis of Right Segment of Solanoeclepin A

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Figshare2016-02-17 更新2026-04-29 收录
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The highly strained tricyclo­[5.2.1.01,6]­decene skeleton of solanoeclepin A was synthesized through two key C–C bond forming processes; thus, a Hg­(TFA)2-mediated oxymercuration followed an intramolecular aldol reaction to B and a SmI2-mediated cyclization of C between an aldehyde and an unsaturated ester to form the cyclobutane D having a tricyclo­[5.2.1.01,6]­dodecene.

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2016-02-17
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