Copper(I)-Catalyzed Regioselective Amination of <i>N</i>‑Aryl Imines Using TMSN<sub>3</sub> and TBHP: A Route to Substituted Benzimidazoles
收藏NIAID Data Ecosystem2026-03-07 收录
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A novel and efficient copper-catalyzed amination of N-aryl imines is described. This one-pot, multicomponent reaction, in which imine acts as a directing group by chelating to the metal center, affords a potential route for the transformation of the commercial aryl amines, aldehydes, and azides into valuable benzimidazole structural units with wide substrate scope and diversity. The synthetic and mechanistic aspects are presented.
创建时间：
2016-02-15
