Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination
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The bis(NHC)borate-supported thorium-bis(mesitylphosphido) complex (1) undergoes reversible intramolecular C–H bond activation enabling the catalytic hydrophosphination of unactivated internal alkynes. Catalytic and stoichiometric experiments support a mechanism involving reactive Th–NHC metallacycle intermediates (Int and 2).
创建时间：
2017-09-12
