Nonmetathetic Activity of Ruthenium Alkylidene Complexes: 1,4-Hydrovinylative Cyclization of Multiynes with Ethylene
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下载链接:
https://figshare.com/articles/dataset/Nonmetathetic_Activity_of_Ruthenium_Alkylidene_Complexes_1_4_Hydrovinylative_Cyclization_of_Multiynes_with_Ethylene/2508424
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资源简介:
An efficient 1,4-hydrovinylative cyclization reaction
of triynes
and tetraynes catalyzed by ruthenium alkylidene complexes under ethylene
is described. The regioselectivity of vinyl group incorporation can
be controlled by the nature of the substituent on the alkyne, and
the Grubbs second-generation catalyst is the most effective among
typical ruthenium alkylidene complexes.
创建时间:
2012-07-04



