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A New Octanuclear Copper(II)−Nucleoside Wheel

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/A_New_Octanuclear_Copper_II_Nucleoside_Wheel/3019318
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The reaction of Cu(CF3SO3)2 and cytidine in aqueous solution leads to the first example of a polynuclear copper(II)−cytidine complex of formula [Cu(H2O)6][Cu8(Hcyd)8(CF3SO3)4](CF3SO3)6·12H2O (H2cyd = cytidine). It shows a fascinating calixarene-like structure made up of octanuclear [Cu8(Hcyd)8(CF3SO3)4]4+ wheel-shaped moieties that show receptor properties through multiple H-bonding interactions toward [Cu(H2O)6]2+ cations occupying the centers of the wheel.
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2007-03-14
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