Octaphenylnaphthalene and Decaphenylanthracene
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https://figshare.com/articles/dataset/Octaphenylnaphthalene_and_Decaphenylanthracene/3658440
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资源简介:
Octaphenylnaphthalene (2) was synthesized by the
addition of tetraphenylbenzyne to tetraphenylcyclopentadienone, and decaphenylanthracene (3) was synthesized by
the addition of the same aryne to hexaphenylisobenzofuran followed by deoxygenation of the adduct. The
structures of both compounds were determined by
X-ray analysis. Compound 2 adopts a conformation of
approximate Ci symmetry with a
slightly undulating naphthalene
nucleus, but compound 3 exhibits
C2 (and approximate
D2) symmetry with a 63° twist of
the central anthracene.
创建时间:
2016-08-18



