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A Direct Metal-Free Decarboxylative Sulfono Functionalization (DSF) of Cinnamic Acids to α,β-Unsaturated Phenyl Sulfones

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https://figshare.com/articles/dataset/A_Direct_Metal_Free_Decarboxylative_Sulfono_Functionalization_DSF_of_Cinnamic_Acids_to_Unsaturated_Phenyl_Sulfones/2206051
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资源简介:
A metal-free room temperature decarboxylative cross-coupling between cinnamic acids and arylsulfonyl hydrazides has been realized for the first time for the synthesis of (E)-vinyl sulfones. The scope and versatility of the reaction has been demonstrated by the regio- and stereoselective synthesis of 22 derivatives with diverse structural features.
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2015-06-05
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