Crystal and Magnetic Structures of Unusually High Valence Fe Materials

Highly oxidized iron oxides such as SrFe4+O3, CaFe4+O3, and CaCu3Fe4O12 display unusual electronic and magnetic behaviors due to the highly covalent nature of the Fe-O...高氧化态铁氧化物，如四价铁酸锶(SrFe4+O3)、四价铁酸钙(CaFe4+O3)以及CaCu3Fe4O12，因Fe-O键的高度共价特性，展现出反常的电子与磁学行为。