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Total Synthesis of (+)- and (−)-Sundiversifolide via Intramolecular Acylation and Determination of the Absolute Configuration

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Total_Synthesis_of_and_Sundiversifolide_via_Intramolecular_Acylation_and_Determination_of_the_Absolute_Configuration/2950450
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资源简介:
Intramolecular acylation of an organolithium leads to an efficient stereocontrolled total synthesis of both enantiomers of sundiversifolide. The absolute configuration was determined by HPLC analysis and allelopathy assay. The γ-lactone moiety resulted from a butenolide was obtained by the condensation of a bicyclic α-hydroxyhemiacetal with Ph3PCMe(CO2R).
创建时间:
2016-06-03
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