Binaphthol-Catalyzed Asymmetric Conjugate Arylboration of Enones
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Conjugate addition of arylboronates to α,β-unsaturated ketones may be catalyzed by chiral binaphthols with enantioselectivities of up to 99:1. Best results were observed with 3,3′-dichloro-BINOL. This chemistry was applied to syntheses of intermediates for syntheses of (+)-indatraline and (+)-tolterodine.
创建时间：
2016-02-22
