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Diastereo- and Enantioselective Pd(II)-Catalyzed Additions of 2‑Alkylazaarenes to N‑Boc Imines and Nitroalkenes

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Diastereo_and_Enantioselective_Pd_II_Catalyzed_Additions_of_2_Alkylazaarenes_to_i_N_i_Boc_Imines_and_Nitroalkenes/2471368
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A chiral Pd­(II)–bis­(oxazoline) complex was found to be highly effective in promoting the first direct diastereo- and enantioselective addition of alkyl­aza­arenes to N-Boc aldimines and nitroalkenes under mild conditions. Deprotection of Boc-protected products proceeded readily to provide amines in high yields.
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2016-02-20
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