Cross Dipole Stacking in the Crystal of Distyrylbenzene Derivative: The Approach toward High Solid-State Luminescence Efficiency

Through adding two substituent phenyl groups on distyrylbenzene, we have obtained the cross stacking of 2,5-diphenyl-1,4-distyrylbenzene with two trans double bonds (trans-DPDSB) in crystalline state. In such a cross-stacking mode, the solid-state emission exhibits high-intensity, having characteristics similar to its single molecule. The organic light-emiiting diodes (OLEDs) with attractive performance have been achieved using trans-DPDSB as a light-emitting layer, and the amplified spontaneous emission of the needlelike crystals has been observed.