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Rhodium-Catalyzed Enantioselective Synthesis, Crystal Structures, and Photophysical Properties of Helically Chiral 1,1′-Bitriphenylenes

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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Enantioselective_Synthesis_Crystal_Structures_and_Photophysical_Properties_of_Helically_Chiral_1_1_Bitriphenylenes/2543599
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The highly enantioselective synthesis of helically chiral 1,1′-bitriphenylenes has been achieved via rhodium-catalyzed double [2 + 2 + 2] cycloaddition of biaryl-linked tetraynes with 1,4-diynes (up to 93% ee). Crystal structures and photophysical properties of these helically chiral 1,1′-bitriphenylenes have also been studied.
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2012-03-07
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