<i>anti</i>-Oligoannelated THF Moieties: Synthesis via <i>Push−Pull</i>-Substituted Cyclopropanes
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The first synthesis of anti-fused oligoannelated THF moieties is reported. The key transformation of the synthetic sequence, consisting of cyclopropanation, reduction and oxidation, is the expansion of a push−pull-substituted three-membered ring into a five-membered enol ether system. A repetition of the sequence allows the creation of oligoacetals up to a nonacyclic system.
创建时间：
2016-02-26
