Huge Magnetic Anisotropy in a Trigonal-Pyramidal Nickel(II) Complex
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The work presented herein shows the experimental and theoretical studies of a mononuclear nickel(II) complex with the largest magnetic anisotropy ever reported. The zero-field-splitting D parameter, extracted from the fits of the magnetization and susceptibility measurements, shows a large value of −200 cm–1, in agreement with the theoretical value of −244 cm–1 obtained with the CASPT2–RASSI method.
创建时间：
2016-02-18
