Reaction of Corey Ylide with α,β-Unsaturated Ketones: Tuning of Chemoselectivity toward Dihydrofuran Synthesis

A straightforward, efficient, and
reliable approach to synthetically
valuable 2,3-dihydrofurans via a reaction between Corey ylide and
α,β-unsaturated ketones has been developed. The use of
simple and widely spread starting materials as well as mild reaction
conditions and scalability provide a broad scope of 2,3-dihydrofurans.