Spatial Recognition Within Terpenes: Redox and H‑bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes
收藏NIAID Data Ecosystem2026-03-11 收录
下载链接：
https://figshare.com/articles/dataset/Spatial_Recognition_Within_Terpenes_Redox_and_H_bond_Promoted_Linkage_Isomerizations_and_the_Selective_Binding_of_Complex_Alkenes/12202637
下载链接
链接失效反馈官方服务：
资源简介：
A method
for the resolution of η2-alkene-complex
isomers of the type MoTp(NO)(DMAP)(η2-alkene) and
WTp(NO)(PMe3)(η2-alkene) (where Tp = hydridotris(pyrazolyl)borate
and DMAP = 4-(dimethylamino)pyridine) has been explored. Alkene and
polyene compounds form as a mixture of kinetically trapped isomers.
For both types of complexes, it was found that addition of either
a fluorinated alcohol or one-electron oxidant reduces the number of
isomers in solution. Accelerated ligand exchange was also observed,
although these reactions were accompanied by significant decomposition.
创建时间：
2020-04-27
