Cationic Vanadium(IV) Methyl Complexes [Cp<sub>2</sub>VMe(CH<sub>3</sub>CN)][B(C<sub>6</sub>H<sub>5</sub>)<sub>4</sub>] and [Cp<sub>2</sub>VMe(THF)][MeB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]
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The cationic vanadocene alkyl complex [Cp2VMe(CH3CN)]+ with [BPh4]- counteranion was structurally established. The reaction of Cp2VMe2 in THF in the presence of B(C6F5)3 is also described: EPR evidence of the intermediate formation of the [Cp2VMe(THF)]+ species, which gives, via a disproportionation redox reaction, the VIII species [Cp2V(THF)][Me B(C6F5)3], is demonstrated.
创建时间：
2016-08-26
