Synthesis and Characterization of an Unsymmetrical 1,2-Diphosphinoethanide Complex
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_an_Unsymmetrical_1_2_Diphosphinoethanide_Complex/2655151
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A palladium 1,2-ethylene-bisphosphine complex prepared by diphosphination of acrylonitrile and subsequent complexation undergoes facile and reversible C deprotonation at a backbone carbon atom. The 1,2-diphosphinoethanide complex that formed was characterized by spectroscopic data and a single-crystal X-ray diffraction study. The reaction may explain the previously observed configurational lability of coordinated 1,2-bisphosphine ligands with electron-withdrawing substituents.
创建时间：
2016-02-23
