An Enantioselective Total Synthesis of (+)-Aigialospirol
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https://figshare.com/articles/dataset/An_Enantioselective_Total_Synthesis_of_Aigialospirol/2976328
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资源简介：
A concise and enantioselective total synthesis of (+)-aigialospirol is described here, featuring the first complex natural product synthesis that
employs a cyclic ketal-tethered ring-closing metathesis strategy and an unexpected stereoselective epimerization of a benzylic hydroxyl group.
The 15-step synthetic sequence illustrates the proof-of-concept that such an approach can be competitive with the classical spiroketal formation
in the natural product synthesis.
创建时间：
2016-06-03
