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Synthesis of Dibenzofurans via Palladium-Catalyzed Phenol-Directed C–H Activation/C–O Cyclization

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Synthesis_of_Dibenzofurans_via_Palladium_Catalyzed_Phenol_Directed_C_H_Activation_C_O_Cyclization/2639878
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资源简介:
A practical, Pd(0)/Pd(II)-catalyzed reaction was developed for phenol-directed C–H activation/C–O cyclization using air as an oxidant. The turnover-limiting step of the process was found to be C–O reductive elimination instead of C–H activation. This reaction can tolerate a variety of functional groups and is complementary to the previous methods for the synthesis of substituted dibenzofurans.
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2016-02-23
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