Layered Organic-Based Metal Iodide−Polyiodide with Unique Mixed-Valent Gold(I/III) Iodide Chains
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https://figshare.com/articles/dataset/Layered_Organic_Based_Metal_Iodide_Polyiodide_with_Unique_Mixed_Valent_Gold_I_III_Iodide_Chains/3331072
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资源简介：
We report the synthesis, optical spectrum, and crystal and electronic
structures of a new organic−inorganic hybrid compound, [(p-NH3C6H4)2CH2]4 [(AuI2)(AuI4)(I2)2(I5)2Cl4], with unique mixed-valent
gold(I/III) chains. The chains feature face-shared octahedral
[AuIAuIIII6]2- units and are embedded within polyiodide layers. The
new mixed-valent gold iodide crystallizes in the orthorhombic space
group Pnnm, with a = 27.0703(2), b = 8.9363(5), c = 18.4280(1) Å, Z = 2, and exhibits an optical band gap of 0.53 eV.
创建时间：
2004-07-26
