<i>N,N</i>′-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene
收藏NIAID Data Ecosystem2026-03-06 收录
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Treatment of an N-heterocyclic carbene that features two amide groups N-bound to the carbene nucleus with various organic isocyanides afforded a new class of ketenimines in yields of up to 96% (isolated). DFT analyses revealed that the carbene exhibits a unique, low-lying LUMO, which may explain the atypical reactivity observed.
创建时间：
2016-02-25
