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Synthesis and Characterization of a Ruthenocene Carboxylate Containing Ruthenium(II) Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_Ruthenocene_Carboxylate_Containing_Ruthenium_II_Complex/3256069
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Reaction of [Ru2(μ-O2CRc)4(MeOH)2](PF6) (Rc = ruthenocenyl) with 1,2-bis(diphenylphosphino)ethane (dppe) results in a “dimer disassembly” that produces the bimetallic [Ru(η2-O2CRc)(dppe)2](PF6), whose structure has been confirmed by X-ray diffraction. The electrochemical properties have been investigated using cyclic and Osteryoung square-wave voltammetry.
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2016-05-05
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