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Heterocyclic Radical Mediated Synthesis and Fluorescence Properties of Conjugated Polyene Ketones

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Heterocyclic_Radical_Mediated_Synthesis_and_Fluorescence_Properties_of_Conjugated_Polyene_Ketones/2630412
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A straightforward route for the preparation of decatetraene diketone derivates is presented. The synthesis has been accomplished by a one-step procedure starting from phenyl-substituted pyrylium perchlorates, and an elaborate heterocyclic α-radical mechanism was proposed. This class of molecules displays a crystallization induced emission enhancement property.
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2016-02-23
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