Toward Perylene Dyes by the Hundsdiecker Reaction
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https://figshare.com/articles/dataset/Toward_Perylene_Dyes_by_the_Hundsdiecker_Reaction/2285494
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资源简介：
An efficient method to synthesize
3,4,9,10-tetrabromoperylenes
is reported under optimized Hunsdiecker conditions. Various octasubstituted
perylenes were obtained by reaction of 1,6,7,12-tetrachloro-3,4,9,10-tetrabromoperylene
with phenol, trimethylsilyl chloride, cooper cyanide, or sulfur via
metal-catalyzed couplings or nucleophilic substitutions. These new
perylenes show completely different optical and redox properties,
thus opening a facile way to develop new chromophophore structures.
创建时间：
2016-02-17
