Synthesis of 1H‑Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis
收藏Figshare2016-05-02 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_1_i_H_i_Indazoles_from_Imidates_and_Nitrosobenzenes_via_Synergistic_Rhodium_Copper_Catalysis/3179887
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Nitrosobenzenes have been used as a convenient aminating reagent for the efficient synthesis of 1H-indazoles via rhodium and copper catalyzed C–H activation and C–N/N–N coupling. The reaction occurred under redox-neutral conditions with high efficiency and functional group tolerance. Moreover, a rhodacyclic imidate complex has been identified as a key intermediate.
创建时间：
2016-05-02
