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Metal Hexacarbonyls
六羰基金属（Metal Hexacarbonyls）
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相关数据集
Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters †
The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradi
NIAID Data Ecosystem90
Unprecedented Chemical Transformation of Semicarbazones Mediated by Wilkinson's Catalyst
para-Nitrobenzaldehyde semicarbazone undergoes an unusual chemical transformation upon reaction with [Rh(PPh3)3Cl] in the presence of trialkyl and dialkylamines (NR2R‘; R = Et, iPr, nBu; R‘ = H or R‘
NIAID Data Ecosystem70
Reductive Cleavage of O -, S -, and N -Organonitroso Compounds by Nickel(I) β-Diketiminates
An electron-rich nickel(I) β-diketiminate cleaves the E−NO bond of O-, S-, and N-organonitroso species to give the nickel nitrosyl [Me3NN]NiNO along with dimeric nickel(II) alkoxide or thiolate comple
NIAID Data Ecosystem30
Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]
The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn
NIAID Data Ecosystem70
New Ruthenium(II) Complexes Bearing N - Heterocyclic Carbenes
N-heterocyclic carbene complexes of ruthenium(II), [CpRu(L*)2Cl] (2) and [CpRu(CO)(L*)Cl] (3) (Cp = η5-C5H5; L* = 1,3-dicyclohexyl-imidazolin-2-ylidene), have been obtained in high yields by reaction
NIAID Data Ecosystem50
