The fluorinated phenoxide OC6F5 forms the stable Eu(II) and Eu(III) derivatives (DME)2Eu(μ-OC6F5)3Eu(μ-OC6F5)3Eu(DME)2 and (DME)2Eu(OC6F5)3, as well as the heterovalent product (DME)2Eu(μ-OC6F5)3Eu(DM

NIAID Data Ecosystem70

Lanthanide Pybox Complexes as Catalysts for Enantioselective Silylcyanation of Aldehydes

不对称催化

镧系配合物

Complexes of lanthanide chlorides with pybox ligands catalyze the enantioselective silylcyanation of aromatic and aliphatic aldehydes with ee's of up to 91% under mild and convenient conditions. Studi

NIAID Data Ecosystem20

Mechanistic Investigation of Inducing Triboluminescence in Lanthanide(III) β‑Diketonate Complexes

摩擦材料

镧系配合物

In this work, we synthesized a series of lanthanide(III) β-diketonate complexes to investigate the induction of triboluminescence. Triboluminescence (TL) spectra, solid-state emission spectra, and lu

NIAID Data Ecosystem70

Modulating Magnetic Dynamics of Three Dy 2 Complexes through Keto–Enol Tautomerism of the o -Vanillin Picolinoylhydrazone Ligand

镧系配合物

单分子磁体

Complexation of dysprosium(III) with the heterodonor chelating ligand o-vanillin picolinoylhydrazone (H2ovph) in the presence of different bases affords three new dinuclear dysprosium(III) coordinatio

NIAID Data Ecosystem40

Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as ThII Synthons

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