Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents
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https://figshare.com/articles/dataset/Highly_Diastereoselective_Synthesis_of_Homoallylic_Alcohols_Bearing_Adjacent_Quaternary_Centers_Using_Substituted_Allylic_Zinc_Reagents/3009880
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资源简介：
Staring from readily available polysubstituted allylic chlorides, a range of polysubstituted allylic zinc chlorides were obtained using a LiCl-mediated zinc dust insertion in 55−84% yield. A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic zinc reagents.
创建时间：
2016-02-29
