Synthesis and Characterization of Aluminum-Containing Tin(IV) Heterobimetallic Sulfides
收藏figshare.com2023-06-01 更新2025-03-26 收录
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Aluminum_Containing_Tin_IV_Heterobimetallic_Sulfides/3227023/1
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Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2
(1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] with Ph2SnCl2, Me2SnCl2, and SnCl4 in THF respectively afforded
LAl(μ-S)2SnPh2 (2), LAl(μ-S)2SnMe2 (3), and LAl(μ-S)2Sn(μ-S)2AlL (4) in moderate yields. Compounds 2, 3, and
4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray
structural analysis.
报道了三种新型含铝锡(IV)异金属硫属化合物。通过[LAl(SLi)2(THF)2]2(1)（L = HC(CMeNAr)2，Ar = 2,6-iPr2C6H3）与Ph2SnCl2、Me2SnCl2及SnCl4分别在THF中的反应，分别得到LAl(μ-S)2SnPh2(2)、LAl(μ-S)2SnMe2(3)及LAl(μ-S)2Sn(μ-S)2AlL(4)，产率适中。化合物2、3和4分别经元素分析、核磁共振、电子轰击质谱及单晶X射线结构分析进行表征。
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