cis-2,5-Diaminobicyclo[2.2.2]octane, a New Scaffold for Asymmetric Catalysis via Salen−Metal Complexes
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_i_cis_i_2_5_Diaminobicyclo_2_2_2_octane_a_New_Scaffold_for_Asymmetric_Catalysis_via_Salen_Metal_Complexes/2656222
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资源简介:
A new C2 symmetric salen scaffold based on cis-2,5-diaminobicyclo[2.2.2]octane has been synthesized that forms complexes with a wide range of metals. The chromium(III) complex is shown to catalyze the hetero-Diels−Alder reaction and the Nozaki−Hiyama−Kishi reaction with high efficiency and excellent stereoselectivity.
创建时间:
2016-02-23



