Highly Efficient Synthesis of a Class of Novel Chiral-Bridged Atropisomeric Monophosphine Ligands via Simple Desymmetrization and Their Applications in Asymmetric Suzuki–Miyaura Coupling Reaction
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https://figshare.com/articles/dataset/Highly_Efficient_Synthesis_of_a_Class_of_Novel_Chiral_Bridged_Atropisomeric_Monophosphine_Ligands_via_Simple_Desymmetrization_and_Their_Applications_in_Asymmetric_Suzuki_Miyaura_Coupling_Reaction/2529616
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资源简介：
A series of novel chiral-bridged atropisomeric monophosphine ligands were synthesized via convenient and simple pathways. The prepared ligands, especially for ligand 7d, were found to be highly effective in the Pd-catalyzed Suzuki–Miyaura coupling reaction. The steric hindrance and electronic effect of substrates on the reactivity and enantioselectivity were explored preliminarily.
创建时间：
2012-04-20
