A Series of Lanthanide-Based Cluster Organic Frameworks Made of Heptanuclear Trigonal-Prismatic Cluster Units
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A series of lanthanide-based cluster organic frameworks, [Ln7(μ3-OH)8L9(H2O)6]·4ClO4·3HL·nH2O [HL = 4-pyridin-4-ylbenzoic acid; Ln = Y (1), La (2), Gd (3), Yb (6), n = 6; Ln = Dy (4), Er (5), n = 4], were hydrothermally made and characterized. It is the first example of heptanuclear trigonal-prismatic lanthanide clusters via a hydrothermal reaction. The magnetic properties of 3 and 4 show typical antiferromagnetic interactions.
创建时间：
2016-02-20
