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Crystal structure of (1,3-di-tert-butyl- η 5-cyclo­penta­dien­yl)tri­methyl­hafnium(IV)

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DataCite Commons2025-11-12 更新2025-04-10 收录
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https://edatos.consorciomadrono.es/citation?persistentId=doi:10.21950/BCYB9Y
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资源简介:
The mol­ecule of the title organometallic hafnium(IV) com­pound, [Hf(CH3) 3(C 13H 21)] or [HfMe3( η 5-C 5H 3-1,3- tBu 2)], adopts the classical three-legged piano-stool geometry for mono­cyclo­penta­dienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclo­penta­dienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant inter­molecular inter­actions present between the mol­ecules in the crystal structure.
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e-cienciaDatos
创建时间:
2019-03-05
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