Wagner–Meerwein-Type Rearrangements of Germapolysilanes - A Stable Ion Study
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Wagner_Meerwein_Type_Rearrangements_of_Germapolysilanes_A_Stable_Ion_Study/2052528
下载链接
链接失效反馈官方服务：
资源简介：
The rearrangement of tris(trimethylsilyl)silyltrimethylgermane 1 to give tetrakis(trimethylsilyl)germane 2 was investigated as a typical example for Lewis acid catalyzed Wagner–Meerwein-type
rearrangements of polysilanes and polygermasilanes. Direct 29Si NMR spectroscopic evidence is provided for several cationic intermediates
during the reaction. The identity of these species was verified by
independent synthesis and NMR characterization, and their transformation
was followed by NMR spectroscopy.
创建时间：
2016-08-04
