Single-Operation Deracemization of 3H-Indolines and Tetrahydroquinolines Enabled by Phase Separation
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https://figshare.com/articles/dataset/Single_Operation_Deracemization_of_3H_Indolines_and_Tetrahydroquinolines_Enabled_by_Phase_Separation/2373544
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资源简介:
The
single-operation deracemization of 3H indolines and tetrahydroquinolines
is described. An asymmetric redox approach was employed, in which
a phosphoric acid catalyst, oxidant, and reductant are present in
the reaction mixture. The simultaneous presence of both oxidant and
reductant was enabled by phase separation and resulted in the isolation
of highly enantioenriched starting materials in high yields.
创建时间:
2016-02-18



