Selectivities in Nickel-Catalyzed Hydrocarboxylation of Enynes with Carbon Dioxide
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https://figshare.com/articles/dataset/Selectivities_in_Nickel-Catalyzed_Hydrocarboxylation_of_Enynes_with_Carbon_Dioxide/5087152
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A three-component hydrocarboxylation of enynes with ZnEt2 and CO2 is realized. Highly selective cyclizative carboxylation of the C–C triple bond was observed. Preliminary mechanistic studies indicated both the concerted cyclometalation mechanism and the stepwise CC bond-directed carboxylation were possible in this reaction.
创建时间：
2017-06-08
