Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Selective_Cyclization_of_Arylnitrones_to_Indolines_under_External_Oxidant_Free_Conditions_Dual_Role_of_Rh_III_Catalyst_in_the_C_H_Activation_and_Oxygen_Atom_Transfer/2174188
下载链接
链接失效反馈官方服务：
资源简介：
The first example of Rh(III)-catalyzed
cyclization of arylnitrones to indolines under external oxidant-free
conditions is presented. An intermolecular coupling of arylnitrones
with internal alkynes is made possible by the dual role of the Cp*Rh(III)
catalyst mediating both the C–H bond activation and O-atom
transfer. Synthetically important and pharmacologically privileged
indoline derivatives were obtained in good yields with high diastereoselectivity.
创建时间：
2016-02-13
