Data underlying the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network

The data underlines the paper: <strong>Temporally programmed polymer-solvent interactions using a chemical reaction network</strong>. In this work a new modular chemical reaction network (CRN) was developed, which enables reversible formation of positive charges on a tertiary amine substrate, which are removed using nucleophilic signals that control the deactivation kinetics. The modular nature of the CRN enables incorporation in diverse polymer materials, leading to a temporally programmed transition from collapsed and hydrophobic to solvated, hydrophilic polymer chains by controlling polymer-solvent interactions. Depending on the layout of the CRN, we can create stimuli-responsive or autonomously responding materials.

本数据集支撑的研究论文为**《使用化学反应网络（chemical reaction network, CRN）实现时间程序化调控的聚合物-溶剂相互作用》。本研究开发了一种全新的模块化化学反应网络（CRN），可在叔胺底物上实现正电荷的可逆生成；通过控制失活动力学的亲核信号，可移除上述正电荷。该CRN的模块化属性使其可被整合至多种聚合物材料中，通过调控聚合物与溶剂的相互作用，实现聚合物链从塌陷疏水状态到溶剂化亲水状态的时间程序化转变。依据CRN的不同布局，可制备出刺激响应型或自主响应型材料。