Interpenetrated Metal–Organic Framework with Selective Gas Adsorption and Luminescent Properties
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https://figshare.com/articles/dataset/Interpenetrated_Metal_Organic_Framework_with_Selective_Gas_Adsorption_and_Luminescent_Properties/2286457
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资源简介：
A new 2-fold interpenetrated cadmium
metal–organic framework
{[Cd2(TPPBDA)(OBA)2]·4DMA·8H2O}n (1) (Cd-MOF) (TPPBDA
= N,N,N′,N′-tetrakis(4-(4-pyridine)-phenyl)biphenyl-4,4′-diamine,
H2OBA = 4,4′-oxybis(benzoate), and DMA = N,N-dimethylacetamide) was synthesized
by a solvothermal reaction. Compound 1 is a 3D net with
a meso-helical chain. A noticeable structural feature is that the
arrangement of lattice DMA molecules is different in the different
meso-helical channels. The material exhibits gas sorption properties
for CO2, H2, and CH4. The adsorption
selectivity of CO2/CH4 was calculated from the
single-component isotherms using the dual-site Langmuir–Freundlich-based
ideal adsorbed solution theory. In addition, the luminescent properties
of the Cd-MOF in the solid state and in suspension in different organic
solvents was investigated.
创建时间：
2016-02-17
