Memory of Chirality in Cascade Rearrangements of Enediynes
收藏NIAID Data Ecosystem2026-03-06 收录
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The cascade rearrangement of chiral enediynes 1c−e, involving successively 1,3-proton shift, Saito−Myers cyclization, 1,5-hydrogen atom transfer, and intramolecular coupling of the resulting biradical, proceeded at 80 °C to form tri- and tetracyclic heterocycles possessing a quaternary stereogenic center with a very high level of memory of chirality.
创建时间：
2010-10-27
