Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
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The treatment of [{Ti(η5-C5Me5)}4(μ3-N)4] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(η5-C5Me5)}4(μ3-N)3(μ3-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].
创建时间：
2016-02-16
