Conformational Polymorphism of Lithium Pinacolone Enolate
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https://figshare.com/articles/dataset/Conformational_Polymorphism_of_Lithium_Pinacolone_Enolate/4229285
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资源简介：
A metastable, polymorphic hexameric
crystal structure of lithium
pinacolone enolate (LiOPin) is reported along with three preparation
methods. NMR-based structural characterization implies that the lithium
pinacolate hexamer deaggregates to a tetramer in toluene but retains
mainly the hexameric structure in nonaromatic hydrocarbon solvents
such as cyclohexane. Moreover, the presence of a small amount of lithium
aldolate (LiOA) dramatically influences the aggregation state of LiOPin
by forming a mixed aggregate with a 3:1 ratio (LiOPin3·LiOA).
创建时间：
2016-11-11
