Copper(I)-Mediated 1,2-Metallate Rearrangements of 1-Metallated Glycals
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0031-1289721
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资源简介：
1,2-Metallate rearrangements involving reaction of 1-metallated glycals with organolithium reagents under copper(I) mediation give alkenylpolyol chains in 45-91% yield (19 examples). The reaction was applied to a formal synthesis of KRN7000 as well as a synthesis of a Δ5,6-ceramide derivative.
提供机构：
Georg Thieme Verlag, Stuttgart, New York
创建时间：
2012-03-20
