Noncovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage
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资源简介：
A dinuclear ruthenium complex, [(η5-indenyl)Ru(CO)2]2, was noncovalently enclathrated within a self-assembled coordination cage. In the cavity, rapid cis–trans isomerization and ligand exchange between the terminal and bridging carbonyls were suppressed, and only the carbonyl-bridged cis configuration was observed by X-ray crystallographic analysis.
创建时间：
2016-02-23
