Structural Impact of Coordinating a Helical 2,6-Pyridyl Diamide with Divalent Metals
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Structural_Impact_of_Coordinating_a_Helical_2_6_Pyridyl_Diamide_with_Divalent_Metals/3049039
下载链接
链接失效反馈官方服务：
资源简介：
The structural consequences of coordinating 2,6-bis[2-((4S)-4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]carbamoylpyridines, 2, with divalent
metals such as Cu(II), Ni(II), and Zn(II) are reported. Metal coordination occurs under mild conditions in a manner that preserves the helical
bias of the parent ligand in the solid state and in solution. 1H NMR line-shape analysis indicates that metal coordination increases the helical
interconversion barrier, thus rigidifying the dynamic helicity of 2.
创建时间：
2006-11-09
