Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
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https://figshare.com/articles/dataset/Enantioselective_Rhodium_III_-Catalyzed_Markovnikov_Hydroboration_of_Unactivated_Terminal_Alkenes/5161579
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资源简介:
We
report the first enantioselective Rh-catalyzed Markovnikov hydroboration
of unactivated terminal alkenes. Using a novel sp2–sp3 hybridized diboron reagent and water as a proton source,
a broad range of alkenes undergo hydroboration to provide secondary
boronic esters with high regio- and enantiocontrol.
创建时间:
2017-11-28



