Silyl–Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum
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https://figshare.com/articles/dataset/Silyl_Silylene_Interplay_in_Cationic_PSiP_Pincer_Complexes_of_Platinum/2201257
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资源简介：
Herein
we report the synthesis and spectroscopic observation of
a Pt complex featuring a P2Si ligand containing
a central silylene donor connected to phosphines via two o-arylene linkers. Species of the type (P2Si)PtR
undergo a net 1,2-migration of R from Pt to Si, which leads to highly
unsaturated Pt cations displaying only a very distant interaction
with the weakly coordinating carborane anion.
创建时间：
2016-02-15
